Determination of rare earth and refractory trace element abundances in early solar system objects by ion microprobe     

S. Sahijpal  K. K. Marhas  J. N. Goswami 《Journal of Earth System Science》2003,112(4):485-498

Experimental and analytical procedures devised for measurement of rare earth element (REE) abundances using a secondary ion mass spectrometer (ion microprobe) are described. This approach is more versatile than the conventional techniques such as neutron activation analysis and isotope dilution mass spectrometry by virtue of its high spatial resolution that allows determination of REE abundances in small domains (10-20 micron) within individual mineral phases. The ion microprobe measurements are performed at a low mass-resolving power adopting the energy-filtering technique (Zinner and Crozaz 1986) for removal and suppression of unresolved complex molecular interferences in the REE masses of interest. Synthetic standards are used for determining various instrument specific parameters needed in the data deconvolution procedure adopted for obtaining REE abundances. Results obtained from analysis of standards show that our ion microprobe may be used for determining REE abundances down to ppm range with uncertainties of ∼ 10 to 15%. Abundances of rare earth and several other refractory trace elements in a set of early solar system objects isolated from two primitive carbonaceous chondrites were determined using the procedures devised by us. The results suggest that some of these objects could be high temperature nebular condensates, while others are products of melting and recrystallization of precursor nebular solids in a high temperature environment.  相似文献   

The pressure–temperature–time path of migmatites from the Sikkim Himalaya     

N. B. W. Harris  M. Caddick  J. Kosler  S. Goswami  D. Vance  A. G. Tindle 《Journal of Metamorphic Geology》2004,22(3):249-264

A combined metamorphic and isotopic study of lit‐par‐lit migmatites exposed in the hanging wall of the Main Central Thrust (MCT) from Sikkim has provided a unique insight into the pressure–temperature–time path of the High Himalayan Crystalline Series of the eastern Himalaya. The petrology and geochemistry of one such migmatite indicates that the leucosome comprises a crystallized peraluminous granite coexisting with sillimanite and alkali feldspar. Large garnet crystals (2–3 mm across) are strongly zoned and grew initially within the kyanite stability field. The melanosome is a biotite–garnet pelitic gneiss, with fibrolitic sillimanite resulting from polymorphic inversion of kyanite. By combining garnet zoning profiles with the NaCaMnKFMASHTO pseudosection appropriate to the bulk composition of a migmatite retrieved from c. 1 km above the thrust zone, it has been established that early garnet formed at pressures of 10–12 kbar, and that subsequent decompression caused the rock to enter the melt field at c. 8 kbar and c. 750 °C, generating peritectic sillimanite and alkali feldspar by the incongruent melting of muscovite. Continuing exhumation resulted in resorption of garnet. Sm–Nd growth ages of garnet cores and rim, indicate pre‐decompression garnet growth at 23 ± 3 Ma and near‐peak temperatures during melting at 16 ± 2 Ma. This provides a decompression rate of 2 ± 1 mm yr^?1 that is consistent with exhumation rates inferred from mineral cooling ages from the eastern Himalaya. Simple 1D thermal modelling confirms that exhumation at this rate would result in a near‐isothermal decompression path, a result that is supported by the phase relations in both the melanosome and leucosome components of the migmatite. Results from this study suggest that anatexis of Miocene granite protoliths from the Himalaya was a consequence of rapid decompression, probably in response to movement on the MCT and on the South Tibetan detachment to the north.  相似文献   

The sensitivity of the northern hemisphere summer mean meridional circulation to changes in the large scale eddy forcing     

B. N. Goswami 《Journal of Earth System Science》1985,94(3):219-235

A zonally averaged version of the Goddard Laboratory for Atmospheric Sciences (GLAS) climate model is used to study the sensitivity of the northern hemisphere (NH) summer mean meridional circulation to changes in the large scale eddy forcing. A standard solution is obtained by prescribing the latent heating field and climatological horizontal transports of heat and momentum by the eddies. The radiative heating and surface fluxes are calculated by model parameterizations. This standard solution is compared with the results of several sensitivity studies. When the eddy forcing is reduced to 0.5 times or increased to 1.5 times the climatological values, the strength of the Ferrel cells decrease or increase proportionally. It is also seen that such changes in the eddy forcing can influence the strength of theNH Hadley cell significantly. Possible impact of such changes in the large scale eddy forcing on the monsoon circulation via changes in the Hadley circulation is discussed. Sensitivity experiments including only one component of eddy forcing at a time show that the eddy momentum fluxes seem to be more important in maintaining the Ferrel cells than the eddy heat fluxes. In the absence of the eddy heat fluxes, the observed eddy momentum fluxes alone produce subtropical westerly jets which are weaker than those in the standard solution. On the other hand, the observed eddy heat fluxes alone produce subtropical westerly jets which are stronger than those in the standard solution.  相似文献   

Quantitative treatment of annealing of charged particle tracks in common minerals     

J.N. Goswami  R. Jha  D. Lal 《Earth and Planetary Science Letters》1984,71(1):120-128

A semi-empirical approach has been used to obtain an analytical expression for the annealing of charged particle tracks in minerals as a function of time and temperature. The new formalism allows quantitative evaluation of the extent of annealing in samples for any specified temperature and track production history. The validity of the present approach depends upon the applicability of the Arrhenius equation to the process of annealing of nuclear tracks in solids. Laboratory track annealing studies confirm the predictive aspects of the present approach and also the applicability of Arrhenius' equation to track annealing over a wide time-temperature range (5 seconds/1200 K to 5 × 10⁶ seconds/500 K). The present quantitative treatment of track annealing in rock minerals should permit an in-depth study of a variety of problems in meteoritics and earth sciences.  相似文献   

Biostratigraphy and floristic evolution of coal swamp floras of a part of Talcher Basin,India: a window on a Permian temperate ecosystem     

Shreerup Goswami  Kamaljyoti Das  Mrutyunjaya Sahoo  Soumyaranjan Bal  Sanghamitra Pradhan  Kamal Jeet Singh  Anju Saxena 《Arabian Journal of Geosciences》2018,11(17):524

The present megafloral assemblage recorded from the Barakar sediments of Dholpahar section along Singda rivulet near Gopal Prasad Village in Talcher Basin comprises of equisetaceous stems, Gangamopteris buriadica, Palaeovittaria kurzii and 19 species of the genus Glossopteris. Record of Gangamopteris, Palaeovittaria and many narrow mesh forms of Glosspteris viz., G. angustifolia, G. churiensis, G. communis, G. recurva, G. spatulata, G. stenoneura, G. tenuifolia, G. vulgaris and G. zeilleri from two older fossiliferous horizons demonstrates that these fossils were preserved during Lower Barakar sedimentation. The report of middle and broad mesh forms of Glossopteris viz., G. barakarensis, G. browniana, G. indica, G. intermittens, G. karharbariensis, G. nakkarea, G. oldhamii, G. taeniensis and G. retifera in the youngest fossiliferous horizons reveals that these fossils were preserved during the deposition of Upper Barakar sediments. The continuation of some of the Karharbari plant fossils in the early phase of Barakar Formation and their disappearance in the flora of Late Barakar suggests a shift in the climatic setup. Palaeoclimate and palaeovegetation of this area are also summarised in this study. Moreover, the fossil assemblages of different fossiliferous beds of Dholpahar section demonstrate the evolution of midrib and meshes in different reticulate leaves.  相似文献   

Effects of humic substances on Fe(II) sorption onto aluminum oxide and clay     

Ying Zhu  Jingjing Liu  Omanjana Goswami  Ashaki A. Rouff  Evert J. Elzinga 《Geochemical transactions》2018,19(1):3

We studied the effects of humic substances (HS) on the sorption of Fe(II) onto Al-oxide and clay sorbents at pH 7.5 with a combination of batch kinetic experiments and synchrotron Fe K-edge EXAFS analyses. Fe(II) sorption was monitored over the course of 4 months in anoxic clay and Al-oxide suspensions amended with variable HS types (humic acid, HA; or fulvic acid, FA) and levels (0, 1, and 4 wt%), and with differing Fe(II) and HS addition sequences (co-sorption and pre-coated experiments, where Fe(II) sorbate was added alongside and after HS addition, respectively). In the Al-oxide suspensions, the presence of HS slowed down the kinetics of Fe(II) sorption, but had limited, if any, effect on the equilibrium aqueous Fe(II) concentrations. EXAFS analyses revealed precipitation of Fe(II)–Al(III)-layered double hydroxide (LDH) phases as the main mode of Fe(II) sorption in both the HA-containing and HA-free systems. These results demonstrate that HS slow down Fe(II) precipitation in the Al-oxide suspensions, but do not affect the composition or stability of the secondary Fe(II)–Al(III)-LDH phases formed. Interference of HS with the precipitation of Fe(II)–Al(III)-LDH was attributed to the formation organo-Al complexes HS limiting the availability of Al for incorporation into secondary layered Fe(II)-hydroxides. In the clay systems, the presence of HA caused a change in the main Fe(II) sorption product from Fe(II)–Al(III)-LDH to a Fe(II)-phyllosilicate containing little structural Al. This was attributed to complexation of Al by HA, in combination with the presence of dissolved Si in the clay suspension enabling phyllosilicate precipitation. The change in Fe(II) precipitation mechanism did not affect the rate of Fe(II) sorption at the lower HA level, suggesting that the inhibition of Fe(II)–Al(III)-LDH formation in this system was countered by enhanced Fe(II)-phyllosilicate precipitation. Reduced rates of Fe(II) sorption at the higher HA level were attributed to surface masking or poisoning by HA of secondary Fe(II) mineral growth at or near the clay surface. Our results suggest that HS play an important role in controlling the kinetics and products of Fe(II) precipitation in reducing soils, with effects modulated by soil mineralogy, HS content, and HS properties. Further work is needed to assess the importance of layered Fe(II) hydroxides in natural reducing environments.  相似文献   

An investigation on the evolution process of thunderstorms over a metropolis of India using DWR Max_Z products and genetic algorithm     

Sutapa Chaudhuri  Fatema Khan  Jayanti Pal  Sayantika Goswami  Anirban Middey 《Meteorology and Atmospheric Physics》2015,127(1):75-93

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Structures and morphotectonic evolution of the frontal fold–thrust belt,Kameng river section,Arunachal Himalaya,India     

T K Goswami  D Bezbaruah  Soumyajit Mukherjee  R K Sarmah  S Jabeed 《Journal of Earth System Science》2018,127(6):88

The Neogene–Quaternary Siwalik foreland fold and thrust belt is studied for better understanding of tectonics along the Kameng river section of Arunachal Pradesh, India. The Kimi, Dafla, Subansiri, and the Kimin Formation correspond to Lower, Middle and Upper Siwaliks, respectively. The lithology in the foreland basin is dominantly sandstones, siltstones, claystones, carbonaceous shales, and boulder beds in the upper part. The structural style of the sedimentary sequence from the Main Boundary Thrust southward shows first order ramp-flat geometry. The brittle shear transfers slip across glide horizons to shallower depth. Repeated splay generations from a major regional-scale floor transfers slip from one glide horizon to another that shortens and thickens the crust. In the micro-scale, the lithological response in the structural development is well documented as pressure solution seams and other diagenetic deformation signatures. The basement asperity plays a significant role as the moving thrust front produced a major lateral ramp. The differential movement of the mountain front on both sides of the ramp is decipherable. This is especially true at the western part of the SE flowing Kameng river. The tectonic evolution of the area initiated with slip along the MBT \(\sim \)11 Ma ago along with the deposition of the Siwalik sediments. With southward propagation of the mountain front, the foreland basin shifted towards S, produced splay thrusts from the Himalayan Frontal Thrust-1 (HFT-1), which has been uplifting the Kimin and the older terraces.  相似文献   

Validation of a satellite-based cyclogenesis technique over the North Indian Ocean     

Suman Goyal  M Mohapatra  Ashish Kumar  S K Dube  Kushagra Rajendra  P Goswami 《Journal of Earth System Science》2016,125(7):1353-1363

Indian region is severely affected by the tropical cyclones (TCs) due to the long coast line of about 7500 km. Hence, whenever any low level circulation (LLC) forms over the Indian Seas, the prediction of its intensification into a TC is very essential for the management of TC disaster. Satellite Application Centre (SAC) of Indian Space Research Organization (ISRO), Ahmedabad, has developed a technique to predict TCs based on scatterometer-derived winds from the polar orbiting satellite, QuikSCAT and Oceansat-II. The India Meteorological Department (IMD) has acquired the technique and verified it for the years 2010–2013 for operational use. The model is based on the concept of analogs of the sea surface wind distribution at the stage of LLC or vortex (T1.0) as per Dvorak’s classifications, which eventually leads to cyclogenesis (T2.5). The results indicate that the developed model could predict cyclogenesis with a probability of detection of 61% and critical success index of 0.29. However, it shows high over-prediction of the model is better over the Bay of Bengal than over Arabian Sea and during post-monsoon season (September–December) than in pre-monsoon season (March–June).  相似文献   

Organization of vertical shear of wind and daily variability of monsoon rainfall     

K. C. Gouda  P. Goswami 《Meteorology and Atmospheric Physics》2016,128(5):565-577

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